Cellulose?Nanofiber?Reinforced Rubber Composites with Resorcinol Resin Prepared by Elastic Kneading
نویسندگان
چکیده
A resorcinol resin/water dispersion and a rubber latex are added to 1% 2,2,6,6,-tetramethylpyperidine-1-oxyl (TEMPO)-oxidized cellulose nanofibers (TEMPO-CNFs) dispersed in water, followed by oven drying at 40 °C for 20 h prepare dried TEMPO-CNF/resorcinol resin/latex (DTRL) mixture with weight ratio of 1/0.5/3. DTRL is then nitrile-butadiene (NBR) or carboxy group-containing NBR (X-NBR) sheet, the kneaded two-roll mill 20–30 high shear forces. The tensile strength Young's modulus crosslinked DTRL/rubber composite sheets remarkably increased from 10 12 MPa, respectively, reference sheet 24 82 containing ?10 vol% TEMPO-CNFs. Scanning electron microscopy revealed that no TEMPO-CNF agglomerates present sheets. properties best when X-NBR used as matrix preparation, respectively. When water-extracted (WDTRL, mass recovery ?94%) place DTRL, WDTRL/rubber show sufficient water resistance, while almost same those
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ژورنال
عنوان ژورنال: Macromolecular Materials and Engineering
سال: 2021
ISSN: ['1439-2054', '1438-7492']
DOI: https://doi.org/10.1002/mame.202100483